Metals and Non-Metals
Compare metals and non-metals, link outer electrons to ion formation, and apply the metallic-to-non-metallic trend across a period.
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The core idea
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Learning objectives
- describe the relationship between number of outer (valence) electrons and the ionic charge of an ion for the first twenty elements
- describe the change from metallic to non-metallic character from left to right across a period of the Periodic Table
- describe the relationship between number of outer (valence) electrons and metallic/non-metallic character
Metals and non-metals show different physical properties and different electron behaviour. Across a period, the elements generally change from metallic to non-metallic character as the number of outer electrons increases.
1. Definition
A. Metal
A metal is an element that typically forms positive ions (cations) and has properties like good electrical conductivity and malleability.
B. Non-metal
A non-metal is an element that typically forms negative ions (anions) or shares electrons (covalent bonding) and is usually a poor electrical conductor.
2. Key Ideas
- Metals tend to lose electrons to form cations (e.g. Na⁺, Mg²⁺).
- Non-metals tend to gain electrons to form anions (e.g. Cl⁻, O²⁻) or form covalent molecules.
- Useful exceptions:
- graphite conducts electricity (non-metal exception), but diamond does not,
- mercury is a liquid metal at room temperature,
- bromine is a liquid non-metal at room temperature,
3. Detailed Explanations
- Metals usually lose electrons to form cations (e.g. Na⁺, Mg²⁺).
- Non-metals usually gain electrons to form anions (e.g. Cl⁻, O²⁻) or form covalent molecules.
- Across a period, character changes from metallic to non-metallic as the number of outer electrons increases.
- Key exceptions to broad physical-property patterns: graphite conducts; mercury is a liquid metal; bromine is a liquid non-metal.
A. Physical properties (comparison table)
| Property | Metals | Non-metals |
|---|---|---|
| appearance | shiny (lustrous) | dull |
| strength | usually strong | usually weak/brittle (if solid) |
| malleable/ductile | yes | no (brittle if solid) |
| state at room temp | mostly solid (except mercury) | many are gases; some solids; bromine is liquid |
| electrical conductivity | good | poor (except graphite) |
| thermal conductivity | good | poor (generally) |
- Graphite is a non-metal but conducts electricity (delocalised electrons).
- Mercury is a metal but is liquid at room temperature.
B. Chemical properties: ions formed (link to bonding)
| Element type | Electron behaviour | Ion formed (typical) | Example |
|---|---|---|---|
| metals | lose electrons | cations | Na → Na⁺ + e⁻ |
| non-metals | gain electrons | anions | Cl + e⁻ → Cl⁻ |
Metals form ionic compounds with non-metals: Ionic Bonding.
Many non-metals form covalent molecules: Covalent Bonding.
C. Metallic to non-metallic character across a period
Across a period, elements generally change from metallic → non-metallic character.
This links strongly to valence electrons (outer electrons):
| Valence electrons (main-group) | Typical character (O-Level) |
|---|---|
| 1–3 | metals (lose electrons to form cations) |
| 4 | often covalent behaviour; carbon and silicon do not usually form simple ions |
| 5–7 | non-metals (gain/share electrons) |
| full outer shell (Group 18) | very unreactive non-metals (noble gases) |
If an unfamiliar element has mixed properties, classify it from the observations supplied rather than relying only on its position.
4. Common Mistakes
- Replacing the requested property comparison with unrelated advanced trends.
- Saying “non-metals do not conduct electricity” without mentioning the graphite exception.
- Mixing up “cation/anion” wording (metals form cations; non-metals form anions).
- Describing the across-period trend without linking it to the increasing number of outer electrons.
5. Exam Tips
State the requested contrasting properties first. Add a named exception only when it is relevant to the question.
- If asked “why conduct electricity?”: metals conduct due to delocalised electrons; graphite conducts due to delocalised electrons between layers.
- For the across-period trend, state both ends: metallic character decreases; non-metallic character increases.
6. Worked Examples
Modelled example 1
Classify and justify
Problem
Study the worked solution
State the classification
Method
Identify magnesium as a metal.Reason
Magnesium lies on the metallic side of the Periodic Table and shows typical metallic properties.Working
Classification: metal.Select observable evidence
Method
Use electrical conductivity or malleability.Reason
Good conduction and ability to change shape without shattering are typical metal properties.Working
For example, magnesium conducts electricity.Write a supported answer
Working
Magnesium is a metal because it conducts electricity; malleability would also support the classification.
Guided practice 2
Across-period trend
Problem
Connect the trend to outer electrons
Hints
Hint 1: name both ends
Hint 2: state both character directions
View solution step by step
State the character trend
Method
Move from sodium towards chlorine.Reason
Elements cross from the metal side towards the non-metal side of the period.Working
Metallic character decreases; non-metallic character increases.Use outer electrons
Method
Increase the number of valence electrons across the period.Reason
The simplest stable electron changes shift from electron loss towards electron gain or sharing.Working
Na tends to lose one electron; chlorine tends to gain one.Link explanation to trend
Working
Increasing outer-electron count supports the change from metallic to non-metallic behaviour.
Common misconception 3
Conductivity exception
Learner response
Identify the mobile charge carrier
View solution step by step
Correct the absolute claim
Method
Replace “never” with a qualified generalisation.Reason
Most non-metals are poor electrical conductors, but graphite is an established exception.Working
Safe claim: non-metals are usually poor conductors.Explain graphite
Method
Identify delocalised electrons in its layered structure.Reason
These electrons can move along the layers and carry electrical charge.Working
Mobile delocalised electrons → graphite conducts.State the correction
Working
Graphite is a conducting non-metal exception because it has mobile delocalised electrons.
Examiner practice 4
Identify the type of ion
Examination question
Give classification, charge and electron direction
View solution step by step
Classify the ion
1 markMethod
Name an anion or halide ion.Reason
Chlorine is a Group 17 non-metal that forms a negative halide ion.Working
Type: halide anion.State the charge
1 markMethod
Write Cl⁻.Reason
The ion has one more electron than the neutral atom.Working
Charge: -1.Explain formation
1 markMethod
Gain one electron.Reason
This completes chlorine’s outer shell.Working
Cl + e⁻ → Cl⁻.
Self-mark with the mark scheme
Compare your response with each mark point. Select a point only when your response contains that evidence.
Self-mark ion type, charge and electron change separately.
Challenge 5
Predict electron behaviour
Position-to-bonding transfer
Move from groups to charges to ratio
Hints
Hint 1: predict electron direction
Hint 2: make charge total zero
View solution step by step
Predict X
Method
Remove two outer electrons from Group 2 element X.Reason
Electron loss gives a cation with charge 2 +.Working
X → X²⁺ + 2e⁻.Predict Y
Method
Add one electron to Group 17 element Y.Reason
Electron gain completes its outer shell and gives charge 1-.Working
Y + e⁻ → Y⁻.Balance the formula
Method
Use two Y ions for each X ion.Reason
1(2 +) + 2(1-) = 0.Working
Neutral formula: XY₂.
7. Mind Stretchers
Mind stretcher 1: Don’t guess the stateExtension
Question: A student writes: “All non-metals are gases.” Correct this with one example.
Show Answer
False. Some non-metals are solids (e.g. carbon, sulfur) and bromine is a liquid at room temperature.
Mind stretcher 2: Use several observationsExtension
Question: Element X is a brittle solid and a poor electrical conductor. Its oxide reacts with an alkali. Is X more likely metallic or non-metallic? Explain using both observations.
Show Answer
X is more likely non-metallic. Brittleness and poor conductivity are typical non-metal properties, while reaction of its oxide with an alkali suggests an acidic oxide, which is typical of non-metals.
8. Quiz
Test typical properties, ion formation, useful exceptions and the metallic-to-non-metallic trend.
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