Acid–base titration lab
Titrate acids and alkalis drop by drop: watch the indicator change, plot the pH curve and find an unknown concentration from concordant titres.
Back to topics: Measurements & Experimental Techniques (G3 Pure Chemistry / O-Level Chemistry)Experimental Chemistry (G3 Science (Chemistry))Chemical Calculations (G3 Science (Chemistry))Acid-Base Chemistry (G3 Science (Chemistry))Stoichiometry & The Mole Concept (G3 Pure Chemistry / O-Level Chemistry)Acids, Bases & Salts (G3 Pure Chemistry / O-Level Chemistry)
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Learning objectives
- describe the meanings of the terms acid and alkali in terms of the ions they produce in aqueous solution and their effects on Universal Indicator
- describe neutrality and relative acidity and alkalinity, in terms of — colour in Universal Indicator, and
- describe neutrality and relative acidity and alkalinity, in terms of — the pH scale (calculation of pH from hydrogen ion concentration is not required)
- describe the reaction between hydrogen ions and hydroxide ions to produce water, H+ + OH– → H2O, as neutralisation
- name appropriate apparatus for the measurement of time, temperature, mass and volume; including burettes, pipettes, measuring cylinders and gas syringes
- use techniques, apparatus and materials;
- make and record observations, measurements and estimates;
- apply the concept of solution concentration (in mol/dm3 or g/dm3) to process the results of volumetric experiments (e.g. titration) and to solve simple problems. (appropriate guidance will be provided where unfamiliar reactions such as redox are involved. Calculations on % yield and % purity are not required.)
- apply the concept of solution concentration (in mol/dm3 or g/dm3) to process the results of volumetric experiments (e.g. titration) and to solve simple problems (appropriate guidance will be provided where unfamiliar reactions are involved)
- explain qualitatively the differences in behaviour between strong and weak acids and bases in terms of the extent of dissociation
- explain the choice of suitable indicators for acid-base titrations, given appropriate data, in terms of the strengths of the acids and bases
- — explain how buffer solutions control pH
- Ka, Kb, Kw, pKa, pKb
- Titration Curves and Indicators
- Buffer Solutions
25.0 cm³ of 0.100 mol/dm³ hydrochloric acid with universal indicator. 0.00 cm³ of 0.100 mol/dm³ sodium hydroxide added; the pH is 1.00 and the solution is red.
- Volume added
- 0.00 cm³
- pH
- 1.00
- [H⁺]
- 0.10 mol/dm³
- Titration
- 1 (rough)
Try this
0 of 4 doneWith universal indicator, add alkali to hydrochloric acid until the solution turns violet. (not done yet)
The colour runs from red through green to violet as OH⁻ ions remove H⁺ ions (H⁺ + OH⁻ → H₂O). Near neutralisation one drop takes the pH from about 4 to 10.
Titrate ethanoic acid with sodium hydroxide to the end point twice: once with methyl orange and once with phenolphthalein. (not done yet)
The steep part runs from about pH 7.5 to 10, so phenolphthalein or thymolphthalein changes within a drop of equivalence. Methyl orange changes in the buffer region, far too early.
Titrate ethanoic acid with sodium hydroxide past equivalence, then drag the graph cursor to the half-equivalence point. (not done yet)
Half the CH₃COOH has become CH₃COO⁻, so the two concentrations are equal and pH = pKₐ = 4.76. Around this point the curve is flattest: the buffer region.
Find the concentration of a sodium hydroxide sample: do a rough titration, then accurate ones until two titres agree within 0.20 cm³. (not done yet)
Average the concordant titres. Moles of HCl = concentration × titre; the 1 : 1 ratio gives the moles of NaOH in 25.0 cm³, so divide by 0.0250 dm³.
Your readings
| # | Final reading / cm³ | Initial reading / cm³ | Titre / cm³ | Remove |
|---|---|---|---|---|
| No readings yet. Set up a measurement, then record it. | ||||