Evaluating practical results and improving a method

ACE (Paper 3): identify random vs systematic errors, explain limitations, and suggest specific, realistic improvements that score marks.

  • SEC G3 Pure Chemistry 2027
On this page

A useful evaluation connects an observation to a possible cause and a specific improvement. Ask what the results support, how much they vary and whether the method could bias them.

What the skill involves

Analysis, conclusions and evaluation (ACE) is a practical assessment skill area. Analyse the results, draw a conclusion supported by them and evaluate the method by identifying limitations and possible improvements.

What you need to know

  • Random error: unpredictable variation (repeats help).
  • Systematic error: a consistent bias (repeats do not fix it).
  • Accuracy: closeness to true value. Precision: closeness of repeats.
  • Improvements must be specific and linked to the error.

Putting the skill into practice

Quick Recall (common Paper 3 words)
  • Accuracy compares a measurement with the true or accepted reference value; precision compares repeated measurements with each other.
  • Repeats reveal the spread. Averaging suitable repeats reduces the influence of random variation, but does not remove a systematic bias.
  • A valid investigation uses a method that answers its question and controls other relevant variables.
  • Investigate an unexpected result, retain the original reading and repeat the trial. Exclude it only with a justified reason.

Random vs systematic error

TypeWhat it looks likeExampleBest improvement
Randomrepeats scatter around a valuereaction start time variesrepeat + mean; better timing
Systematicreadings biased in a consistent directionbalance reads +0.10 g alwayscalibrate/zero; check instrument

Visual example (random scatter vs systematic offset):

Random vs Systematic Error (Example)

Example data showing random scatter around a true value versus systematic error with a consistent offset.

Scroll across the graph to read all labels.

Example data showing random scatter around a true value versus systematic error with a consistent offset.Example data showing random scatter around a true value versus systematic error with a consistent offset.
Random error gives scattered repeats around a value. Systematic error shifts every result up/down by a similar amount.
Open full-size graph
View figure data
Values and uncertainty for Random vs Systematic Error (Example)
SeriesTrial number (unitless)Trial number uncertaintyMeasured mass (g)Measured mass uncertainty
True value (2.00 g)12
True value (2.00 g)52
Random error (scattered repeats)11.97
Random error (scattered repeats)22.03
Random error (scattered repeats)31.99
Random error (scattered repeats)42.02
Random error (scattered repeats)51.98
Systematic +0.05 g (precise but inaccurate)12.05
Systematic +0.05 g (precise but inaccurate)22.05
Systematic +0.05 g (precise but inaccurate)32.05
Systematic +0.05 g (precise but inaccurate)42.05
Systematic +0.05 g (precise but inaccurate)52.05

“limitation” vs “mistake”

  • A limitation is a weakness in the method (even if you followed it correctly).
  • A mistake is an error in carrying out the method. Explain how it affects the result and how to prevent it, rather than naming “human error” alone.

Matching an improvement to its cause

Bad: “reduce human error”.

Good (specific + linked):

  • “Use a gas syringe instead of observing bubbles so volume can be measured accurately.”
  • “Repeat the reaction at each temperature, record the spread and calculate a mean of valid trials. Investigate unusual results and repeat any trial with an identified fault.”
  • “Use a burette to deliver a variable liquid volume with a smaller reading uncertainty than the available measuring cylinder.”
Make a repeat plan specific

State which measurement you will repeat, the conditions you will keep the same and how you will use the results. Choose enough repeats to check their agreement; three trials can be a useful starting plan, rather than a rule for every experiment.

A constant offset can cancel when you subtract two readings. For example, if a thermometer reads 2°C too high both before and after mixing, each temperature is wrong but the calculated temperature change is unchanged. This cancellation relies on the offset being the same for both readings.

Avoiding common mistakes

  • Writing “human error” with no specific cause.
  • Suggesting impossible improvements (e.g., “use a more accurate stopwatch” without explaining timing method).
  • Confusing accuracy with precision.
  • Not stating the direction of bias when it is obvious (e.g., “gas leaked → volume too low”).

Explaining your method

Connect cause, effect and improvement

“A limitation is … therefore the results may be … (too high/too low).”
“To improve accuracy/precision, … because …”
“Repeat the measurement under the same conditions, inspect the spread and calculate a mean of valid results to reduce random variation.”

Worked examples

Modelled example 1

Leak in Gas Syringe Setup

Core

Problem

A small leak exists at the bung while a gas syringe measures product volume. State the direction of the measurement error and a specific improvement.
Study the worked solution
  1. Trace the lost gas

    Method

    State that some product gas escapes through the leak.

    Reason

    Escaped gas never enters the syringe barrel.

    Working

    Collected volume is less than the volume actually produced.
  2. State the bias and fix

    Method

    Conclude that readings are too low and make the apparatus airtight.

    Reason

    A tight-fitting bung and checked tubing prevent systematic gas loss.

    Working

    Bias: volume too low. Improvement: secure and leak-test all connections before starting.

Common misconception 2

Accuracy vs Precision

Find and correct the mistake

Learner claim

The true mass is 2.00 g. Student A records 2.00, 2.00, 2.00 g; Student B records 2.05, 2.05, 2.05 g. A learner says B is imprecise because every value is wrong. Correct the precision and accuracy judgements.

Judge agreement separately from truth

Student B precision
More accurate student

View solution step by step
  1. Judge precision

    Method

    Call both sets precise.

    Reason

    Each student’s repeated readings agree closely with one another.

    Working

    A: precise; B: also precise.
  2. Judge accuracy

    Method

    Identify A as more accurate and B as systematically high.

    Reason

    Accuracy compares with the true 2.00 g value; B is offset by + 0.05 g every time.

    Working

    A is precise and accurate; B is precise but inaccurate.

Challenge 3

Inconsistent End-Point (Cross Disappears)

Minimal support

Evaluation transfer

Times for a disappearing-cross endpoint are scattered. Explain the likely random-error source and propose changes that improve reliability.

Link the subjective observation to improvements

Likely source
Reliability improvement

Hints

Hint 1: endpoint
Ask whether different observers would decide “disappeared” at exactly the same instant.
Hint 2: consistency
Control observer, viewing distance, lighting and solution depth, then use repeated measurements.
View solution step by step
  1. Identify the random source

    Method

    Attribute scatter to subjective endpoint judgement and reaction time.

    Reason

    The precise stopping instant varies unpredictably from trial to trial.

    Working

    Random error in observing and timing the cross disappearance.
  2. Improve consistency and reliability

    Method

    Use the same observer, viewing distance, lighting and depth of solution. Repeat under the same conditions and calculate a mean of valid trials.

    Reason

    Controlled viewing reduces variation, while repeats reveal anomalies and reduce the influence of random error.

    Working

    Standardise observation + repeat and mean.

Try it independently

Mind stretcher 1: Spot the Systematic ErrorExtension

Question: A thermometer reads 2°C too high for every measurement. Are repeats enough to fix this? What should you do?

Show Answer

Answer: Repeats do not fix a systematic error. You should calibrate/replace the thermometer or correct every reading by subtracting 2°C (if instructed/justified).

Mind stretcher 2: Weak ImprovementExtension

Question: A student writes: “Use a different method.” Why is this not a good evaluation answer, and what is a better one?

Show Answer

Answer: It is too vague and does not show understanding. A better answer states a specific method change, e.g., “Use a burette to deliver this variable volume, reducing reading uncertainty compared with the available measuring cylinder.”

Practise and check

Topic check

See what you know across this topic, then go back to anything you got wrong.

Take the topic check

Syllabus and review details

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